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PICVD Coating Technology


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Abstract-- Plastic containers with a gas barrier and chemical resistance.

(sidebar: The PICVD applied silicon dioxide layer on the inside of a PET bottle prevents the ingress of oxygen and the egress of carbon dioxide that would affect the taste of the product.)


Because of their manifest benefits as packaging materials, many manufacturers have converted from glass and metal packaging to plastics. Plastics do not, however, have the barrier to gases or the chemical resistance of glass. As a result, there has been a continuous search for ways to improve the barrier properties of plastics to accommodate more and more sensitive products or to increase the shelf life of products already packed in plastic containers. Product areas that require a better barrier include carbonated beverages (soft drinks and beer), fruit juice, cosmetics, chemicals and pharmaceuticals. There is a desire, for example, to pack many more products in PET because of its transparency and brilliance - similar to glass, but lighter to handle and unbreakable. PET does not, however, have the barrier to oxygen and carbon dioxide demanded by many products. A 50-nm internal coating of silicon dioxide applied by the PICVD process can provide this necessary oxygen barrier to protect the contents and increase the shelf life of the products.

The PICVD applied silicon dioxide layer on the inside of a PET bottle prevents the ingress of oxygen and the egress of carbon dioxide that would affect the taste of the product.

Due to the numbers involved and the economics, it is not possible to ship PET containers around the country for coating. The coating process has to be applied in or at least close to the blow molding plant. SCHOTT HiCotec already has experience in the design and construction of PICVD plants and the integration of these plants into commercial production. In order to meet the requirements for the coating of PET bottles, SCHOTT HiCottec has concluded an exclusive joint development in the food and beverage area with SIG Corpoplast, a leading manufacturer of high-volume two-stage machinery for the blow molding of PET containers. The result is a barrier coating machine that reflects the complementary expertises of both companies. The first machine, which can coat 10,000 PET containers per hour, will be delivered to the lead customer in the spring of 2003. In the process, the internal surface of the bottle is coated, which has many benefits. A better barrier on PET containers is an essential for further growth in the industry and the transparent PICVD coating meets all the requirements without detracting from one of the essential properties of PET - its clarity. In addition, the silicon dioxide is non-toxic and does not affect the recyclability of the PET.

The PICVD (Plasma Impulse Chemical Vapor Deposition) coating significantly reduces the penetration of oxygen or the loss of carbon dioxide through plastic packages and thus permits a significant increase in the shelf life of the contents.

About Schott HiCotec:

SCHOTT HiCotec designs and builds complete coating plants that can be integrated into the production lines of its customers.

SCHOTT HiCotec, a division of SCHOTT Spezialglas GmbH is a specialist company in the field of coatings initially developed for glass. More recently this same coating technology has been successfully applied to enhance the properties of a number of commercially important plastic materials. The company's program includes the complete development of the required technology - from first sample to industrial-scale production, as well as the design and construction of coating machines.

Schott Brochure "Barriercoating" pdf.file


SCHOTT GLAS
Hattenbergstr. 10
55122 Mainz
Germany
+49 (0)6131/66-0 +49 (0)6131/66-2000
E-Mail: info@schott.com

SCHOTT HiCotec
A Business Segment of SCHOTT Spezialglas GmbH
Hattenbergstrasse 10
55122 Mainz
Germany
Tel.: +49 (0)6131/66-46454 Fax.: +49 (0)6131/66-46491
E-Mail: info.hicotec@schott.com


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Source: SCHOTT HiCotec

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