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2007-05-03 News Release

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Nanotechnology Self Cleaning Effects for Textiles

Through nanotechnology Mincor TX TT, an innovative composite finishing material from BASF, emulates nature by keeping dirt and water at bay.

 

The lotus plant’s extraordinary ability to keep itself clean by means of the ultrafine surface structures on its leaves has led to Buddhism’s holy flower becoming rather a celebrity in our latitudes, too. Yet we can also observe this self-cleaning effect on our own indigenous plants such as the nasturtium, reed or lady’s mantle: water droplets just roll off the surface of their leaves, taking particles of dirt along with them. Learning from nature’s example, science has recognized that it is not the smoothest possible surfaces but those with structures measuring some dozens of nanometers that repel dirt and water most effectively.

Find Information and Suppliers of treated fabrics.

About ten years ago, dirt repellent wall paints were the first marketed products to technically utilize this self-cleaning effect. With Mincor* TX TT, BASF is now starting a new chapter: this innovative polymer finishing material endows technical textiles for awnings, sunshades, sails and tents with the same self-cleaning effect as the lotus. What on the surface of the plant leaves are tiny papillae, on treated textiles are innumerable particles with a diameter of less than 100 nanometers embedded in a carrier matrix. Whether nature or technology – the effect is the same: these tiny nubs keep water droplets and particles of dirt at bay. This is why, on the lotus plant only two to three percent of the droplet surface is in contact with the plant leaf. Because this minimal contact is confined to the outermost tips of the papillae, the adhesive forces that would otherwise cause a droplet to spread are also minimal. Instead, the water’s surface tension forces prevail and invariably cause the droplet to form a spherical globule – and the water just rolls off. Particles of dirt on the surface, which because of the papillae also have hardly any contact with the leaf surface or the fabric treated with Mincor TX TT, are carried along by the droplets and washed away without any need for detergents or scrubbing.

Water droplets on a polyester fabric finished with Mincor TX TT from BASF

Water droplets on a polyester fabric finished with Mincor TX TT from BASF. Click Here for High resolution image. photo: BASF

The principle sounds simple, but its practical implementation on textiles with the aid of Mincor TX TT was a challenge for BASF’s nanotechnologists. The main objective was to optimize the processing and durability of the finishing. “The solution is a composite material consisting of nanoparticles firmly embedded in a carrier matrix”, explains Dr. Ralf Norenberg, Head of BASF’s Competence Center for Technical Textiles. The resulting composite has the required nanostructured surface, but does not release any nanoparticles, as extensive tests have proved.

In 2006, polyester awning fabrics finished with Mincor TX TT were very successful in achieving the transition from the laboratory to practical application, and fabrics for sunshades and sails treated with Mincor TX TT are also now in the trial phase. “This type of finishing is an ideal solution for these kind of fabrics that are continuously exposed to the outdoor elements and can’t be put in a washing machine”, says Norenberg. “The next shower of rain simply washes off the dirt, and in prolonged periods of dry weather all that’s needed is a brief shower from the garden hose.”

“With Mincor TX TT, BASF has for the first time made it possible to provide textiles with a genuine self-cleaning effect based on nanostructured surfaces like its model in nature”, comments Dr. Thomas Stegmaier of the Denkendorf Institute of Textile and Process Engineering (ITV). Countless products are now claimed to have a “lotus” or “nano” effect in order to boost their market potential. But these advertising claims are not always well founded: at most one third of these products, estimates Stegmaier, meet accepted definitions of nanotechnology as used for example by the German Ministry of Education and Research (BMBF). “To provide guidance for consumers at least where textiles are concerned, we have devised the seal of quality ‘Selfcleaning inspired by nature’ – and the first products that meet our strict standards for self-cleaning textiles and have been awarded the seal are polyester fabrics finished with Mincor TX TT.”

Tiny nanoparticles keep water and dirt at bay. Because of their minimal contact surface, the dirt is washed away without trace by the water droplets

Tiny nanoparticles keep water and dirt at bay. Because of their minimal contact surface, the dirt is washed away without trace by the water droplets. Click Here for High resolution image. photo:

The Prospects

Mincor TX TT is already proving its worth on polyester awning fabric. Self-cleaning sunshades, flags and sails made from the finished synthetic fabric are approaching market launch. But the work of BASF’s researchers is still not finished, because the self-cleaning effect for textiles is also planned to make its mark in other areas of daily life in the near future – especially for dirt-repellent clothing. Here, the first challenge was also one of the toughest: the washing machine. During washing, textiles are subjected to enormous mechanical stress that gives the nanoscopic surface structures of the Mincor finishing a tough time.

By optimizing the binder, BASF’s development experts have succeeded in giving Mincor much greater stability without having to make compromises on the self-cleaning effect. “Basically, almost all types of textiles are suitable, but we first concentrated on providing cotton with a washing stable finishing of Mincor”, explains Dr. Michael Schmitt, Head of the Global Development Unit for Textile Auxiliaries. Especially high-quality textiles and working clothes subject to heavy stress and which are difficult to clean could benefit from Mincor. But the Mincor effect, which makes balsamico vinegar, red wine, ketchup and even honey roll off completely without trace, could also mean fewer wash cycles for all other types of clothing. All that is needed is a very thin layer of the composite material which doesn’t impair the feel of the fabric in any way. While the market launch of cotton fabrics and textiles treated with Mincor is imminent, BASF is already working on further applications, such as treated surfaces for dirt repellent wallpapers, soiling sensitive curtains and flawless kitchen frontages would also be interesting.

*Mincor is a registered trademark of BASF.

Find information about BASF Corporation.

Read a recent press release about - Novel Encapsulated Additives Technology enables equivalent UV protection in waterborne coatings to that of high-performance light stabilizers in solventborne coatings.


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