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2006-10-26 News Release

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Biodiesel is environmentally friendly, but perishable

Baynox plus stabilizes biodiesel made from soya and vegetable oils with polyunsaturated fatty acid methyl esters can now be stabilized sufficiently.

 

Increasing the shelf life of environmentally friendly fuel. Just as vegetable oils quickly perish and go rancid in contact with air, there is also a risk that biodiesel will be oxidized by the air too. This involves free fatty acids forming in the biodiesel that have a corrosive effect on the engine. At the same time, polymers may form into “gums” and leave deposits and residues in the engine. As the use of biodiesel becomes more widespread, storage and transportation times – from the production date to refueling at the pump – are getting longer and longer. There is an increasing risk that the biodiesel will become rancid before use. It is thus essential to stabilize biodiesel using antioxidants. LANXESS was therefore quick to develop a suitable biodiesel stabilizer, Baynox*, to keep biodiesel “fresh” for longer. It has an excellent effect in biodiesel produced from rapeseed oil, waste cooking oils, animal fat or palm oil.

Find Information and Suppliers of biodiesel fuel stabilizers.

Stabilizing of biodiesel made from soybean oil. Click Go for High resolution image. photo: Lanxess AG

To stabilize biodiesel made from vegetable oils and containing a large quantity of polyunsaturated fatty acid methyl esters such as soy oil, sunflower seed oil and even Jatropha nut oil, LANXESS searched for antioxidants that would offer reliable protection, as biodiesel obtained from soy oil is more cost-effective but more perishable than the rapeseed oil variety. The result of this research is the new biodiesel stabilizer Baynox* plus. Even quantities of 250 to 500 ppm are effective in sufficiently stabilizing soybean oil biodiesel over six hours in the Rancimat test for pure soya methyl ester. This exceeds the requirements of Europe-wide standard EN 14 214. Baynox plus exhibits the same effect with biodiesel made from sunflower oil and jatropha nut oil – all highly unsaturated vegetable oils.

The Europe-wide standard for biodiesel, EN 14 214, requires the stability of biodiesel to be measured by the Rancimat test at a temperature of 110 °C. The minimum permissible value is six hours. However, the plant’s natural antioxidant, Vitamin E, is often not sufficiently present in biodiesel to ensure compliance with this standard. A synthetic stabilizer therefore needs to be added to increase shelf life. For a non-distilled, commercially available rapeseed biodiesel, it is generally sufficient to add 200 – 400 ppm of Baynox to achieve stability readings of over nine hours.

LANXESS has been supporting the biodiesel industry since its inception. Says Dr. Axel Ingendoh, biodiesel expert in the Basic Chemicals business unit: “Our research activities not only include examining the stability of customer samples and providing recommendations for appropriate, economic dosing, but also meeting continuously increasing market demands by systematically developing and enhancing our range of products. The latest example of this is the development of Baynox plus.”

The production of Baynox and Baynox plus is certified in accordance with ISO 9001 and has been awarded “no harm” status by the German mineral oil industry. This shows that the biodiesel stabilizer from LANXESS can be used to enhance the shelf life of pure biodiesel and in biodiesel that is added (B5) to mineral diesel. An application has already been made for a “no harm” certificate for Baynox plus. “Our products are of a consistently high quality, do not contain sulfur or nitrogen, and combust without leaving residues in the engine,” stresses Ingendoh.

* Baynox is a registered trademark of Lanxess AG.

Find more information about Lanxess AG.

Read a recent press release about - The sodium form of the sulfonate anchor groups that ion exchange resins contain can adsorb the chemical compounds of glycerine and other impurities in biodiesel production.


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